Yeah, a few airlines fly from Brazil to Europe, both direct and with layovers.
Some common ones are:
• LATAM Airlines – flights from cities like São Paulo and Rio to Europe.
• TAP Air Portugal – tons of service between Brazil and Portugal, plus connections across Europe.
• Air France – flights from Brazil to Paris.
• KLM – flights to Amsterdam from major Brazilian cities.
• Lufthansa – connections between Brazil and Germany.
• Iberia – flights between Brazil and Madrid.
• British Airways – flights from Brazil to London.